Hydration Enthalpy Calculator

Calculate hydration enthalpies of ions and predict solubility of ionic compounds in water.

Select Ions

Enter as positive value

Enthalpy Cycle:

Delta H(solution) = Lattice Energy + Delta H(hydration)

Enthalpy of Solution

+18 kJ/mol

Endothermic

+Na+ Hydration
-406 kJ/mol
-Cl- Hydration
-363 kJ/mol
HTotal Hydration
-769 kJ/mol
LLattice Energy
+787 kJ/mol

Solubility Prediction

Soluble

Entropy-driven dissolution

Charge Density:

Na+:

224962.89 C/pm3

Cl-:

40260.18 C/pm3

Hydration Enthalpy Trends

Hydration enthalpy becomes more exothermic (more negative) with smaller ionic radii and higher charges due to stronger ion-dipole interactions with water molecules. This explains why small, highly charged ions have very negative hydration enthalpies.

Group 1 Cations

Li+ > Na+ > K+ > Rb+ > Cs+

Halide Anions

F- > Cl- > Br- > I-